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in this study, we proposed a fabrication method of semitransparent perovskite pv microcells for colored solar windows. the semitransparent perovskite pv microcells were fabricated through a single-step one-pot solution process using a spin-coating method of the perovskite precursor solution. this fabrication method enables the semitransparent perovskite pv microcell with an average ar of 85%, which was confirmed by a transmittance-photovoltage measurement (supplementary fig. 12a ). in addition, the semitransparent perovskite pv microcells showed high pce of the microcells of 8.4% and a light-to-electricity conversion efficiency of 1.42% (supplementary fig. 12b ), indicating that the semitransparent perovskite pv microcells can be applied for high-efficiency colored solar windows for buildings.


this study suggests that the formation of the perovskite nanostructures is an important factor to determine the performance of semitransparent perovskite pv microcells. the perovskite nanostructures were formed from the perovskite precursor solution by a two-step process: the first step is the spin-coating of the precursor solution to make a perovskite film on a glass substrate, and the second step is the thermal annealing of the perovskite film at 150 c to form the perovskite nanostructures. in addition, the formation of the perovskite nanostructures can be controlled by tuning the annealing temperature, and the perovskite nanostructures were formed on the glass substrate. the formation of the perovskite nanostructures was confirmed by sem images (fig. 1c, supplementary fig. 1, 2 ), as well as by the time-resolved photoluminescence (pl) measurements (fig. 1d ). the perovskite nanostructures act as a scattering medium, which significantly improves the ar of the perovskite pv microcells. the perovskite nanostructures also provide a surface for the formation of the perovskite pv microcells. in addition, the perovskite nanostructures would help to increase the surface area of the perovskite pv microcells, which also improves the pces of the perovskite pv microcells. therefore, the perovskite nanostructures significantly improve the performance of the semitransparent perovskite pv microcells. we also demonstrated the application of the perovskite pv microcells for colored solar windows. the fabricated semitransparent perovskite pv microcells successfully functioned as semitransparent perovskite pvs for colored solar windows with a light color by using the proper amount of lead iodide of the perovskite pv microcells. the fabricated semitransparent perovskite pv microcells (1.5% scale) can be further applied to semitransparent perovskite pvs for a thin-film solid-state device, which would significantly improve the performance of the semitransparent perovskite pvs for a thin-film solid-state device. 3d9ccd7d82






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